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引用本文:   张丽丽, 李洁, 陈长宝, 朱树华, 周杰, 尚鹏鹏. 三聚氰胺分子印迹表面等离子体共振传感器的制备及分析应用. 分析化学, 2018, 46(1): 88-93. doi:  10.11895/j.issn.0253-3820.170003 [复制]

Citation:   ZHANG Li-Li, LI Jie, CHEN Chang-Bao, ZHU Shu-Hua, ZHOU Jie, SHANG Peng-Peng. Preparation of Melamine Molecularly Imprinted Surface Plasmon Resonance Sensor and Its Analytical Application. Chinese Journal of Analytical Chemistry, 2018, 46(1): 88-93. doi: 10.11895/j.issn.0253-3820.170003 [复制]

三聚氰胺分子印迹表面等离子体共振传感器的制备及分析应用

通讯作者:  尚鹏鹏, ppshang@sdau.edu.cn

收稿日期: 2017-01-03

接受日期: 2017-11-23

出版日期: 2018-01-20

基金项目: 本文系国家自然科学基金项目(Nos.31370686,31470686)资助

Preparation of Melamine Molecularly Imprinted Surface Plasmon Resonance Sensor and Its Analytical Application

Corresponding author:  SHANG Peng-Peng, ppshang@sdau.edu.cn

Received Date:  2017-01-03

Accepted Date:  2017-11-23

Published Date:  2018-01-20

Fund Project:  This work was supported by the National Natural Science Foundation of China (Nos. 31370686, 31470686)

以合成的烯丙基-1,3,5-三嗪-2,4,6-(1H,3H,5H)三酮为功能单体,三聚氰胺为模板分子,乙二醇二甲基丙烯酸酯为交联剂,在表面等离子体共振(SPR)传感芯片上合成了分子印迹聚合物薄膜。根据印迹聚合物的朗格缪尔方程式,计算得到三聚氰胺和分子印迹聚合物之间的结合常数为1.40×108 L/mol。此传感器显示出对模板分子三聚氰胺的高选择性,在pH=7.5的条件下,此传感器对三聚氰胺的响应最佳,线性范围为0.1-10.0 nmol/L(R=0.9991)。将此传感器用于牛奶和奶粉中三聚氰胺的检测,检出限分别为62.6 pmol/L和56.4 pmol/L(S/N=3),回收率分别为91.5%和92.0%。

关键词:   三聚氰胺, 分子印迹, 表面等离子体共振传感器
Key words:   Melamine, Molecular imprinting, Surface plasmon resonance sensor
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目录

三聚氰胺分子印迹表面等离子体共振传感器的制备及分析应用

张丽丽, 李洁, 陈长宝, 朱树华, 周杰, 尚鹏鹏

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