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引用本文:   李颖, 徐文凯, 李苹, 朱小雪, 黄艳凤, 张纪梅. Fe3O4/MnO2掺杂石墨烯基分子印迹杂化材料用于水环境中17β-雌二醇的电化学传感检测. 分析化学, 2018, 46(7): 1047-1054. doi:  10.11895/j.issn.0253-3820.171195 [复制]

Citation:   LI Ying, XU Wen-Kai, LI Ping, ZHU Xiao-Xue, HUANG Yan-Feng, ZHANG Ji-Mei. Molecularly Imprinted Polymer Electrochemical Sensor Based on Fe3O4/MnO2 Doped Graphene Composites for Determination of 17β-Estradiol in Aquatic Environment. Chinese Journal of Analytical Chemistry, 2018, 46(7): 1047-1054. doi: 10.11895/j.issn.0253-3820.171195 [复制]

Fe3O4/MnO2掺杂石墨烯基分子印迹杂化材料用于水环境中17β-雌二醇的电化学传感检测

通讯作者:  李颖, ly@tjpu.edu.cn; 黄艳凤, huangyanfeng121@163.com

收稿日期: 2017-08-24

接受日期: 2018-03-30

出版日期: 2018-07-10

基金项目: 本文系国家自然科学基金项目(Nos.21106101,21475095)、天津市自然科学基金项目(No.13JCQNJC06300)和中国博士后基金项目(No.2013M540281)资助

Molecularly Imprinted Polymer Electrochemical Sensor Based on Fe3O4/MnO2 Doped Graphene Composites for Determination of 17β-Estradiol in Aquatic Environment

Corresponding author:  LI Ying, ly@tjpu.edu.cn; HUANG Yan-Feng, huangyanfeng121@163.com

Received Date:  2017-08-24

Accepted Date:  2018-03-30

Published Date:  2018-07-10

Fund Project:  This work was supported by the National Natural Science Foundation of China (Nos. 21106101, 21475095), the Natural Science Foundation of Tianjin, China (No.13JCQNJC06300) and Postdoctoral Foundation of China (No. 2013M540281)

采用可逆加成-断裂链转移(Reversible addition fragmentation chain transfer,RAFT)分子印迹技术,以内分泌干扰物17β-雌二醇(17β-estradiol,17β-E2)作为模板分子,以甲基丙烯酸(Methacrylic acid,MAA)为功能单体,二乙烯基苯(Divinyl benzene,DVB)为交联剂,Fe3O4/MnO2掺杂的石墨烯(RGO)为载体,成功制备了Fe3O4/MnO2掺杂石墨烯基分子印迹杂化材料(Fe3O4/MnO2-MIP@RGO),构建了基于Fe3O4/MnO2-MIP@RGO修饰电极的分子印迹电化学传感器。研究结果表明,Fe3O4/MnO2-MIP@RGO修饰电极对17β-E2的线性响应范围为4.0 nmol/L~0.8 μmol/L(R=0.9852),检出限为47.2 pmol/L(3σ),相对标准偏差(RSD)为2.1%~2.5%。本研究为水环境中痕量17β-E2的特异性识别检测提供了一种简单、高效、经济的分析方法。

关键词:   可逆加成-断裂链转移分子印迹技术, 石墨烯, 电化学传感器, 金属氧化物, 17β-雌二醇
Key words:   Reversible addition fragmentation chain transfer molecularly imprinting technique, Reduced graphene oxide, Electrochemical sensor, Metal oxide, 17β-Estradiol
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目录

Fe3O4/MnO2掺杂石墨烯基分子印迹杂化材料用于水环境中17β-雌二醇的电化学传感检测

李颖, 徐文凯, 李苹, 朱小雪, 黄艳凤, 张纪梅

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