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引用本文:   张颖, 汪虹敏, 王小静, 王赛, 崔菁菁, 李传顺, 刘季花. 深海沉积物元素现场测定及方法对比研究. 分析化学, 2018, 46(4): 570-577. doi:  10.11895/j.issn.0253-3820.171204 [复制]

Citation:   ZHANG Ying, WANG Hong-Min, WANG Xiao-Jing, WANG Sai, CUI Jing-Jing, LI Chuan-Shun, LIU Ji-Hua. On-site Determination of Element Concentrations in Marine Sediments and Comparative Study of Analytical Methods. Chinese Journal of Analytical Chemistry, 2018, 46(4): 570-577. doi: 10.11895/j.issn.0253-3820.171204 [复制]

深海沉积物元素现场测定及方法对比研究

通讯作者:  刘季花, jihliu@fio.org.cn

收稿日期: 2017-08-28

接受日期: 2018-01-22

出版日期: 2018-04-01

基金项目: 本文系国际海域资源调查与开发"十三五"规划项目(Nos.DY135-R2-1-01,DY135-R2-1-03)和国家自然科学基金项目(No.41606075)资助

On-site Determination of Element Concentrations in Marine Sediments and Comparative Study of Analytical Methods

Corresponding author:  LIU Ji-Hua, jihliu@fio.org.cn

Received Date:  2017-08-28

Accepted Date:  2018-01-22

Published Date:  2018-04-01

Fund Project:  This work was supported by the China Ocean Mineral Resources Research and Development Association Research Program (Nos.DY135-R2-1-01, DY135-R2-1-03), and the National Natural Science Foundation of China (No.41606075)

应用Epsilon 3x系列小型台式能量色散X射线荧光光谱仪(EDXRF)对采集的印度洋深海沉积物样品进行现场元素分析,并与电感耦合等离子体发射光谱仪(ICP-OES)、电感耦合等离子体质谱仪(ICP-MS)两种仪器的实验室测试数据进行了对比分析。结果表明,8种主量元素(Al、Mg、Fe、K、Ca、Mn、P、Ti)和16种微量元素(Ba、Sr、V、Zn、Zr、Co、Ni、Cu、Ga、Rb、Y、Nb、Mo、Nd、Pb、Th)分析数据的一致性良好,具有很好的线性相关性,主量元素除Al,微量元素除含量低于30 μg/g的Ga、Nb、Th外,相关系数都大于0.9;同时,对部分元素在不同浓度范围下的平均相对偏差进行了计算。研究表明,小型台式EDXRF现场测定值具有很高的准确度和可靠性,这为大洋现场调查中及时了解矿产资源的分布情况提供了新的方法和重要的技术手段。

关键词:   能量色散X射线荧光光谱法, 电感耦合等离子体发射光谱法, 电感耦合等离子体质谱法, 深海沉积物, 现场元素分析
Key words:   Energy dispersive X-ray fluorescence spectrometer, Inductively coupled plasma-optical emission spectrometry, Inductively coupled plasma-mass spectrometry, Marine sediments, On-site element analysis
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深海沉积物元素现场测定及方法对比研究

张颖, 汪虹敏, 王小静, 王赛, 崔菁菁, 李传顺, 刘季花

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