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引用本文:   张勇, 刘劲风, 易润豪, 艾思凡, 成焕仁, 贾文志. 一种黄酮类荧光探针的合成及用于肼的检测. 分析化学, 2018, 46(4): 511-516. doi:  10.11895/j.issn.0253-3820.171222 [复制]

Citation:   ZHANG Yong, LIU Jin-Feng, YI Run-Hao, AI Si-Fan, CHENG Huan-Ren, JIA Wen-Zhi. Synthesis and Application of A Flavone-based Fluorescent Probe for Detection of Hydrazine. Chinese Journal of Analytical Chemistry, 2018, 46(4): 511-516. doi: 10.11895/j.issn.0253-3820.171222 [复制]

一种黄酮类荧光探针的合成及用于肼的检测

通讯作者:  张勇, zy0340907@163.com

收稿日期: 2017-09-04

接受日期: 2018-01-26

出版日期: 2018-04-01

基金项目: 本文系国家自然科学基金项目(No.21603069)、湖北省教育厅高校青年教师深入企业行动计划(No.XD2014677)和湖北理工学院大学生科技创新专项研究项目(No.17cx08)资助

Synthesis and Application of A Flavone-based Fluorescent Probe for Detection of Hydrazine

Corresponding author:  ZHANG Yong, zy0340907@163.com

Received Date:  2017-09-04

Accepted Date:  2018-01-26

Published Date:  2018-04-01

Fund Project:  This work was supported by the National Natural Science Foundation of China (No.21603069), Young College Teachers' Entering into Enterprises Program of Hubei Provincial Department of Education (No.XD2014677) and College Students' Science and Technology Innovation Project of Hubei Polytechnic University(No.17cx08)

以3-羟基黄酮为荧光团,设计合成了一种用于检测肼的荧光增强型探针ZY8,研究了其光谱性质。结果表明,在Tris-HCl/乙醇溶液(9:1,V/V,pH 7.40)中,ZY8对N2H4具有较好的选择性和专一性。在1.6×10-7~6.2×10-5 mol/L浓度范围内,N2H4的浓度与ZY8的荧光强度呈现良好的线性关系,检出限为1.6×10-7 mol/L。ZY8自身荧光微弱,向其中加入N2H4后,荧光增强9倍左右,而且在波长365 nm的紫外光照射下,溶液的颜色由浅灰绿色变成了明亮的草绿色,可实现对N2H4的可视化识别。它可在接近生理pH范围内对N2H4进行检测,响应快,抗干扰能力强。ZY8制成的试纸能裸眼检测低于mmol/L级别的N2H4溶液,将其应用于不同水样中N2H4的检测,N2H4的回收率在96.0%-104.2%之间,相对标准偏差(RSD)小于4%,表明ZY8在环境污染监测领域有潜在的应用价值。

关键词:   , 荧光探针, 3-羟基黄酮
Key words:   Hydrazine, Fluorescent probe, 3-Hydroxyflavone
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一种黄酮类荧光探针的合成及用于肼的检测

张勇, 刘劲风, 易润豪, 艾思凡, 成焕仁, 贾文志

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