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引用本文:   解雪乔, 蔡云凤, 韩娟, 王赟, 陈桐, 李静. 一种亲水性温敏聚合物荧光探针的制备及用于农产品中铝离子的检测. 分析化学, 2018, 46(4): 502-510. doi:  10.11895/j.issn.0253-3820.171392 [复制]

Citation:   XIE Xue-Qiao, CAI Yun-Feng, HAN Juan, WANG Yun, CHEN Tong, LI Jing. Synthesis of A New Type of Responsive Hydrophilic Block Copolymer Fluorescence Probe and Its Application in Detection of Aluminum Ion in Agricultural Products. Chinese Journal of Analytical Chemistry, 2018, 46(4): 502-510. doi: 10.11895/j.issn.0253-3820.171392 [复制]

一种亲水性温敏聚合物荧光探针的制备及用于农产品中铝离子的检测

通讯作者:  韩娟, hjkwb@163.com

收稿日期: 2017-11-06

接受日期: 2018-01-19

出版日期: 2018-04-01

基金项目: 本文系太仓市科技发展计划项目(No.TC2015NY05)、江苏省高校自然科学研究面上项目(16KJB550010)、镇江市重点研发计划项目(No.SH2016019)和江苏出入境检验检疫局科技计划项目(No.2017KJ47)资助

Synthesis of A New Type of Responsive Hydrophilic Block Copolymer Fluorescence Probe and Its Application in Detection of Aluminum Ion in Agricultural Products

Corresponding author:  HAN Juan, hjkwb@163.com

Received Date:  2017-11-06

Accepted Date:  2018-01-19

Published Date:  2018-04-01

Fund Project:  This work was supported by the Project of Science and Technology Development Plan of Taicang (No.TC2015NY05), the Natural Research Project of the Jiangsu Higher Education Institutions of China (No.16KJB550010), Zhenjiang Social Development Project (No.SH2016019) and the Science Foundation of Jiangsu Entry-exit Inspection Quarantine Bureau (No.2017KJ47)

设计合成了一种亲水性温敏聚合物荧光探针,用于检测农产品中的Al3+。通过可逆加成-断裂链转移(RAFT)聚合合成此聚合物荧光探针(L64-BTPA-SHMA),用1H NMR对其进行表征,并通过荧光光谱对聚合物探针的识别性能进行了研究。结果表明,此聚合物荧光探针检测Al3+的荧光响应信号受温度影响显著,温度越高,荧光强度越低。聚合物荧光探针在25℃和pH 7.4的缓冲溶液中对Al3+有良好的选择性识别作用,且基本不受其它金属离子的影响。建立了基于此聚合物探针对Al3+的荧光检测方法,响应信号与Al3+浓度在2.0~18.0 μmol/L范围内呈线性关系,相关系数为0.9977,检出限为1.43 μmol/L。此聚合物荧光探针可应用于检测农产品中Al3+残留,具有良好的实际应用价值。

关键词:   聚合物荧光探针, 铝离子, 检测, 温度响应, 水溶性
Key words:   Polymer fluorescent probe, Aluminum ion, Detection, Temperature response, Water solubility
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目录

一种亲水性温敏聚合物荧光探针的制备及用于农产品中铝离子的检测

解雪乔, 蔡云凤, 韩娟, 王赟, 陈桐, 李静

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