会员登陆: 用户名:  密码: 验证码:
首页 杂志概况 投稿须知 在线投稿 在线阅读 征订启事 广告服务 行业资讯 企业动态 资料中心  专访报道 会展信息 ENGLISH

引用本文:   姜媛媛, 陈传霞, 倪朋娟, 逯一中. 负载于三维镍网上的磷化钴纳米珠链阵列的高效水电解性能研究. 分析化学, 2018, 46(4): 550-555. doi:  10.11895/j.issn.0253-3820.181009 [复制]

Citation:   JIANG Yuan-Yuan, CHEN Chuan-Xia, NI Peng-Juan, LU Yi-Zhong. Efficient Water Splitting Catalyzed by Cobalt Phosphide Nanobead-chain Like Nanoarrays Supported on Three Dimensional Nickel Foam. Chinese Journal of Analytical Chemistry, 2018, 46(4): 550-555. doi: 10.11895/j.issn.0253-3820.181009 [复制]

负载于三维镍网上的磷化钴纳米珠链阵列的高效水电解性能研究

通讯作者:  姜媛媛, mse_jiangyy@ujn.edu.cn; 逯一中, mse_luyz@ujn.edu.cn

收稿日期: 2018-01-05

接受日期: 2018-02-08

出版日期: 2018-04-01

基金项目: 本文系国家自然科学基金项目(No.21705056)和山东省自然科学基金项目(Nos.ZR2018BB057,ZR2018PB009,ZR2017MB022)资助

Efficient Water Splitting Catalyzed by Cobalt Phosphide Nanobead-chain Like Nanoarrays Supported on Three Dimensional Nickel Foam

Corresponding author:  JIANG Yuan-Yuan, mse_jiangyy@ujn.edu.cn; LU Yi-Zhong, mse_luyz@ujn.edu.cn

Received Date:  2018-01-05

Accepted Date:  2018-02-08

Published Date:  2018-04-01

Fund Project:  This work was supported by the National Natural Science Foundation of China (No.21705056) and the Natural Science Foundation of Shandong Province, China (Nos. ZR2018BB057, ZR2018PB009, ZR2017MB022)

研究廉价且高效的水分解电催化剂对于氢能源的开发利用具有重要意义,过渡金属磷化物是最有前景的水分解双功能电催化剂之一。本研究采用先水热法,再低温磷化的简单的两步合成法,在三维镍网上生长CoP纳米珠链阵列,所生成的镍网(Nickel foam,NF)负载CoP纳米珠线阵列(CoP/NF),具有规则的形貌、较大的比表面积,在碱性条件下对氢气析出反应(HER)和氧气析出反应(OER)都表现出良好的电催化性能。在电流密度达到10 mA/cm2时的过电位分别为280 mV(OER)及95 mV(HER)。利用此CoP/NF复合材料组成的双电极体系可以有效电解水,在电流密度为10 mA/cm2时所需的施加电压仅为1.63 V,并且表现出非常高的稳定性。

关键词:   磷化钴, 双功能电催化剂, 氢析出反应, 氧析出反应, 水电解
Key words:   Cobalt Phosphide, Bifunctional electrocatalyst, Hydrogen evolution reaction, Oxygen evolution reaction, Water splitting
[1]

Turner J A. Science, 2004, 305(5686): 972-974. doi: 10.1126/science.1103197

[2]

Li N, Yin Y, Xin S, Li J, Yu G. Small Methods, 2017, 1(6): 1700094-. doi: 10.1002/smtd.v1.6

[3]

Zou X, Zhang Y. Chem. Soc.Rev., 2015, 44(15): 5148-5180. doi: 10.1039/C4CS00448E

[4]

Hou Y, Zhuang X, Feng X. Small Methods, 2017, 1(6): 1700090-. doi: 10.1002/smtd.v1.6

[5]

Wang P, Song F, Amal R, Ng Y H, Hu X. ChemSusChem, 2016, 9(5): 472-477. doi: 10.1002/cssc.201501599

[6]

Wang J, Cui W, Liu Q, Xing Z, Asiri A M, Sun X. Adv. Mater., 2016, 28(2): 215-230. doi: 10.1002/adma.201502696

[7]

Zeng K, Zhang D. Prog. Energy Combust., 2011, 37(5): 631-631

[8]

Sivanantham A, Ganesan P, Shanmugam S. Adv. Func. Mater., 2016, 26(26): 4661-4672. doi: 10.1002/adfm.v26.26

[9]

Stern L, Feng L, Song F, Hu X. Energy Environ. Sci., 2015, 8(8): 2347-2351. doi: 10.1039/C5EE01155H

[10]

Wang Jiong, Zhang Hua, Wang Xin. Small Methods, 2017, 1(6): 1700118-. doi: 10.1002/smtd.v1.6

[11]

Wang X, Li W, Xiong D, Petrovykh D Y, Liu L. Adv. Funct. Mater., 2016, 26(23): 4067-4077. doi: 10.1002/adfm.v26.23

[12]

Chen G F, Ma T Y, Liu Z Q, Li N, Su Y Z, Davey K, Qiao S Z. Adv. Funct. Mater., 2016, 26(19): 3314-3323. doi: 10.1002/adfm.201505626

[13]

Wang C, Jiang J, Ding T, Chen G, Xu W, Yang Q. Adv. Mater. Interface, 2016, 3(4): 1500454-. doi: 10.1002/admi.201500454

[14]

Yang J, Zhang F, Wang X, He D, Wu G, Yang Q, Hong X, Wu Y, Li Y. Angew. Chem. Int. Ed., 2016, 55(41): 12854-12858. doi: 10.1002/anie.201604315

[15]

Wang Y, Kong B, Zhao D, Wang H, Selomulya C. Nano Today, 2017, 15: 26-55. doi: 10.1016/j.nantod.2017.06.006

[16]

Shi Y, Zhang B. Chem. Soc. Rev., 2016, 45(6): 1529-1541. doi: 10.1039/C5CS00434A

[17]

Tian J, Liu Q, Asiri A M, Sun X. J. Am. Chem. Soc., 2014, 136(21): 7587-7590. doi: 10.1021/ja503372r

[18]

Grosvenor A P, Wik S D, Cavell R G, Mar A. Inorg. Chem., 2005, 44(24): 8988-8898. doi: 10.1021/ic051004d

[19]

Li H, Yang P, Chu D, Li H. Appl. Catal. A, 2007, 325(1): 34-40. doi: 10.1016/j.apcata.2007.02.007

[20]

Anantharaj S, Ede S R, Sakthikumar K, Karthick K, Mishra S, Kundu S. ACS Catal., 2016, 6(12): 8069-8097. doi: 10.1021/acscatal.6b02479

[21]

Huang Z, Chen Z, Chen Z, Lv C, Humphrey M G, Zhang C. Nano Energy, 2014, 9: 373-382. doi: 10.1016/j.nanoen.2014.08.013

[22]

Pan Z, Zheng Y, Guo F, Niu P, Wang X. ChemSusChem, 2017, 10(1): 87-90. doi: 10.1002/cssc.201600850

[23]

Ryu J, Jung N, Jang J H, Kim H J, Yoo S J. ACS Catal., 2015, 5(7): 4066-4074. doi: 10.1021/acscatal.5b00349

[24]

Chen G, Ma T, Liu Z, Li N, Su Y, Davey K, Qiao S. Adv. Funct. Mater., 2016, 26(19): 3314-3323. doi: 10.1002/adfm.201505626

[25]

Jin Y, Wang H, Li J, Yue X, Han Y, Shen P, Cui Y. Adv. Mater., 2016, 28(19): 3785-3790. doi: 10.1002/adma.201506314

[26]

Jiang Y, Lu Y, Lin J, Wang X, Shen Z. Small Methods, 2018, : 1700369-. doi: 10.1002/smtd.201700369

计量
  • PDF下载量(10)
  • 文章访问量(275)
  • HTML全文浏览量(0)

目录

负载于三维镍网上的磷化钴纳米珠链阵列的高效水电解性能研究

姜媛媛, 陈传霞, 倪朋娟, 逯一中

Figures and Tables