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引用本文:   邓伟, 卿湘东, 陈铭, 吴康佳, 雷坚志, 陈畅亚, 许素文, 李双双, 文瑾, 申湘忠. 化学计量学辅助三维室温磷光法快速测定大气污染源样品中苊含量. 分析化学, 2018, 46(9): 1438-1445. doi:  10.11895/j.issn.0253-3820.181151 [复制]

Citation:   DENG Wei, QING Xiang-Dong, CHEN Ming, WU Kang-Jia, LEI Jian-Zhi, CHEN Chang-Ya, XU Su-Wen, LI Shuang-Shuang, WEN Jin, SHEN Xiang-Zhong. Chemometrics-assisted Three-dimensional Room Temperature Phosphorescence for Rapid Quantitative Determination of Acenaphthene Contents in Air-pollution Samples. Chinese Journal of Analytical Chemistry, 2018, 46(9): 1438-1445. doi: 10.11895/j.issn.0253-3820.181151 [复制]

化学计量学辅助三维室温磷光法快速测定大气污染源样品中苊含量

通讯作者:  卿湘东, xdqing123@hnu.edu.cn

收稿日期: 2018-03-10

接受日期: 2018-07-05

出版日期: 2018-09-01

基金项目: 本文系国家自然科学基金项目(No.21707032)、湖南省教育厅科学研究重点项目(No.16A109)和湖南人文科技学院校级国家培育基金项目(No.2016PY04)资助

Chemometrics-assisted Three-dimensional Room Temperature Phosphorescence for Rapid Quantitative Determination of Acenaphthene Contents in Air-pollution Samples

Corresponding author:  QING Xiang-Dong, xdqing123@hnu.edu.cn

Received Date:  2018-03-10

Accepted Date:  2018-07-05

Published Date:  2018-09-01

Fund Project:  This work was supported by the National Natural Science Foundation of China (No. 21707032), the Research Foundation of Education Bureau of Hunan Province, China (No. 16A109) and the School-level Supports for National Foundation Cultivation of Hunan University of Humanities, Science and Technology, China (No. 2016PY04)

建立了基于交替三线性分解的化学计量学辅助三维室温磷光法(ATLD-TRTP)快速准确检测大气污染源样品中多环芳烃苊(ACE)的方法。对采集的大气污染源,如餐厨油污、油烟气和烟囱灰等样品,经过简单的样品预处理后,采用荧光光谱仪的磷光模式进行测量,并对获得的激发发射矩阵三维磷光数阵采用ATLD算法进行分解。在n=5时,获得ACE的平均回收率分别为90.5%±7.9%、99.4%±6.1%和101.4%±10.9%,预测均方根误差(RMSEP)分别为0.25、0.12和0.20 μg/mL,检出限(LOD)分别为39.2、18.9和31.0 ng/mL。结果表明,ATLD-TRTP方法能够在背景干扰共存下,快速检测大气污染源样品中ACE的含量,且方法准确、绿色环保,为研究大气颗粒物中PAHs的来源提供了一种很有潜力的分析手段。

关键词:   交替三线性分解, 室温磷光法, , 餐厨油污, 油烟气, 烟囱灰
Key words:   Alternating trilinear decomposition, Room temperature phosphorescence, Acenaphthene, Greasy dirt, Oil smoke, Flue dust
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目录

化学计量学辅助三维室温磷光法快速测定大气污染源样品中苊含量

邓伟, 卿湘东, 陈铭, 吴康佳, 雷坚志, 陈畅亚, 许素文, 李双双, 文瑾, 申湘忠

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