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引用本文:   崔光文, 何润合, 药健, 王建平, 张兴祥. 全固态锌离子选择性电极的制备与表征. 分析化学, 2018, 46(10): 1669-1676. doi:  10.11895/j.issn.0253-3820.181198 [复制]

Citation:   CUI Guang-Wen, HE Run-He, YAO Jian, WANG Jian-Ping, ZHANG Xing-Xiang. Preparation and Characterization of All-Solid-State Zinc Ion Selective Electrode. Chinese Journal of Analytical Chemistry, 2018, 46(10): 1669-1676. doi: 10.11895/j.issn.0253-3820.181198 [复制]

全固态锌离子选择性电极的制备与表征

通讯作者:  王建平, wangjianping@tjpu.edu.cn

收稿日期: 2018-03-25

接受日期: 2018-08-01

出版日期: 2018-10-20

基金项目: 本文系国家自然科学基金项目(No.51573135)资助

Preparation and Characterization of All-Solid-State Zinc Ion Selective Electrode

Corresponding author:  WANG Jian-Ping, wangjianping@tjpu.edu.cn

Received Date:  2018-03-25

Accepted Date:  2018-08-01

Published Date:  2018-10-20

Fund Project:  This work was supported by the National Natural Science Foundation of China (No. 51573135)

锌是人体不可缺少的微量元素,锌的摄入量会影响人的身体健康。因此对食物、药品及环境水样中Zn2+含量的准确检测十分必要。本研究将包含ZnCl2溶液的聚吡咯微胶囊涂敷于玻碳电极与Zn2+选择膜之间,作为固接传感层,制得以聚吡咯微胶囊为中间层的全固态Zn2+选择性膜电极(GC/PPy微胶囊/Zn2+-ISE),以循环伏安法、交流阻抗谱等对电极性能进行了研究。结果表明,聚吡咯微胶囊作为固接传感层,可以明显地提高电极的电容,降低电极的电荷转移阻抗,使电极能有效进行离子电子之间信号的转换。电极的线性响应范围为1×10-5~1.0×10-1 mol/L,检出限为2.45×10-6 mol/L。以聚吡咯为中间层的电极具有良好的再现性和稳定性。

关键词:   聚吡咯微胶囊, 锌离子选择性电极, 全固态选择性电极, 离子检测
Key words:   Polypyrrole microcapsule, Zinc ion selective electrode, All-solid-state selective electrode, Detection of ion
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全固态锌离子选择性电极的制备与表征

崔光文, 何润合, 药健, 王建平, 张兴祥

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