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引用本文:   于皓, 万正妍, 朱国栋, 戴勇, 王彦博, 刘建允. 静电纺丝法制备氧化锆纳米纤维修饰玻碳电极用于甲基对硫磷的检测. 分析化学, 2018, 46(12): 1982-1989. doi:  10.11895/j.issn.0253-3820.181505 [复制]

Citation:   YU Hao, WAN Zheng-Yan, ZHU Guo-Dong, DAI Yong, WANG Yan-Bo, LIU Jian-Yun. Electrospun Zirconia Nanofibre-modified Glassy Carbon Electrode for Determination of Methyl Parathion. Chinese Journal of Analytical Chemistry, 2018, 46(12): 1982-1989. doi: 10.11895/j.issn.0253-3820.181505 [复制]

静电纺丝法制备氧化锆纳米纤维修饰玻碳电极用于甲基对硫磷的检测

通讯作者:  刘建允, jianyun.liu@dhu.edu.cn

收稿日期: 2018-08-02

接受日期: 2018-08-28

出版日期: 2018-12-20

基金项目: 本文系国家自然科学基金项目(Nos.21476047, 21776045)资助

Electrospun Zirconia Nanofibre-modified Glassy Carbon Electrode for Determination of Methyl Parathion

Corresponding author:  LIU Jian-Yun, jianyun.liu@dhu.edu.cn

Received Date:  2018-08-02

Accepted Date:  2018-08-28

Published Date:  2018-12-20

Fund Project:  This work was supported by the National Natural Science Foundtion of China (Nos.21476047, 21776045)

通过静电纺丝技术制备含有锆盐的纳米纤维, 经煅烧制得结构均匀的氧化锆(ZrO2)纳米纤维。纤维直径约为(194±30) nm, 透射电镜及X-射线衍射分析结果表明, 纤维主要由单斜相纳米ZrO2微晶组成。将ZrO2纤维和导电炭黑Super P及粘结剂混合, 采用滴涂法制备ZrO2纳米纤维薄膜修饰玻碳电极, 并成功应用于甲基对硫磷(MP)的检测。利用循环伏安(CV)及差分脉冲伏安法(DPV)研究MP在电极表面的电化学行为。在最优条件下, 响应电流信号与MP的浓度在0.1~1.2 μg/L的范围内呈良好的线性关系, 检出限为0.06 μg/L (S/N=3.0)。此修饰电极具有良好的稳定性、重现性和选择性。使用此传感器检测实际水样, MP的回收率为96.7%~102.4%, 相对标准偏差为2.3%~4.5%, 可望用于MP的高灵敏传感。

关键词:   氧化锆, 电化学传感器, 甲基对硫磷, 纳米纤维
Key words:   Zirconia, Electrochemical sensor, Methyl parathion, Nanofibres
[1]

George T S, Giles C D, Menezes B D. Plant Soil, 2018, 427(1): 191-208

[2]

Zhu J, Qu B, Li M. Int. Biodeter. Biodegr., 2017, 124: 304-313. doi: 10.1016/j.ibiod.2017.05.010

[3]

GB 3838-2002.Environmental Quality Standards for Surface Water.National Standard of the People's Republic of China

地表水环境质量标准.中华人民共和国国家标准.GB 3838-2002

[4]

Virginia C F, Maria F, Joao P J P, Jose M O, Valentina F D, Cristina D M. J. Chromatogr. A, 2018, 1566(7): 1-12

[5]

Surma M K, Sadowska-Rociek A B, Cieslik E J. Food. Anal. Method, 2014, 7(2): 366-376. doi: 10.1007/s12161-013-9635-3

[6]

Sharafi K, Fattahi N, Mahvi A H. J. Sep. Sci., 2015, 38(6): 1010-1016. doi: 10.1002/jssc.201401209

[7]

Lu Q J, Wang H Y, Liu Y L, Hou Y X, Li H T, Zhang Y Y. Biosens. Bioelectron., 2017, 89(1): 411-416

[8]

Viswanathan S, Radecka H, Radecka J. Monatsh. Chem., 2009, 140(8): 891-899. doi: 10.1007/s00706-009-0143-5

[9]

Sipa K, Brycht M, Leniart A, Nosal-Wiercinska A, Skrzypek S. Anal. Chim. Acta, 2018, 1030(7): 61-69

[10]

Kumaravel A, Chandrasekaran M. J. Agric. Food Chem., 2015, 63(27): 6150-6156. doi: 10.1021/acs.jafc.5b02057

[11]

Yang M, Xie T F, Peng L, Zhao Y Y, Wang D J. Appl. Phys. A, 2007, 89(2): 427-430. doi: 10.1007/s00339-007-4204-5

[12]

YU Hui-Cheng, HUANG Xue-Yi, WEI Yi-Chun, LEI Fu-Hou, TAN Xue-Cai, WU Hai-Ying. Chinese J. Anal. Chem., 2014, 42(11): 1661-1666. doi: 10.11895/j.issn.0253-3820.140550

余会成, 黄学艺, 韦贻春, 雷福厚, 谭学才, 吴海鹰. 分析化学, 2014, 42(11): 1661-1666. doi: 10.11895/j.issn.0253-3820.140550

[13]

Dai Y, Zhu G D, Shang X H, Zhu T Z, Yang J M, Liu J Y. Electrochem. Commun., 2017, 81: 14-17. doi: 10.1016/j.elecom.2017.05.017

[14]

ZHAN Pan, DU Xiao-Wen, GAN Ning, LIN Sai-Chai, LI Tian-Hua, CAO Yu-Ting, SANG Wei-Guo. Chinese J. Anal. Chem., 2013, 41(6): 828-834

詹盼, 杜晓雯, 干宁, 林赛钗, 李天华, 曹玉廷, 桑卫国. 分析化学, 2013, 41(6): 828-834

[15]

Rao X X, Hu S B. Mater. Rev., 2007, 21(8): 143-146

[16]

Zhang Z H, Chen H, Wang C X, Chen K Q, Lu X Y, Ouyang P K, Fa J. Fuel, 2018, 230: 211-217. doi: 10.1016/j.fuel.2018.05.018

[17]

AN Feng-Xia, FENG Huan, LIU Jing-Liang, LI Hu-Huan. Environmental Engineering, 2018, 36(2): 60-65

安风霞, 冯欢, 刘景亮, 李沪浣. 环境工程, 2018, 36(2): 60-65

[18]

Wang M, Li Z Y. Sens. Actuators B, 2008, 133(2): 607-612. doi: 10.1016/j.snb.2008.03.023

[19]

Yang Y Q, Tu H Y, Zhang A D, Du D, Lin Y H. J. Mater. Chem., 2012, 22(11): 4977-4981. doi: 10.1039/c2jm15129d

[20]

Alvarado N, Romero J, Torres A, Dicastillo C L, Rojas A, Galotto M J, Guarda A. J. Food Eng., 2018, 217: 1-10. doi: 10.1016/j.jfoodeng.2017.08.008

[21]

Pan D Y, Zhang J C, Li Z, Wu M H. Adv. Mater., 2010, 22(6): 734-738. doi: 10.1002/adma.v22:6

[22]

Espinoza-Gonzalez R, Mosquera E, Moglia I, Villarroel R, Fuenzalida V M. Ceram. Int., 2014, 40(10): 15577-15584. doi: 10.1016/j.ceramint.2014.07.034

[23]

Xiao J, Han Q L, Yu F Y, Zhang Y J, Wu H, Li X, Zeng X Y, Dong P, Liu J. J. Alloy. Compd., 2018, 731: 1080-1088. doi: 10.1016/j.jallcom.2017.10.130

[24]

Yang M M, Luo X D, Yi J, Yu M, Zhang X F. Ceram. Int., 2018, 44(11): 12664-12669. doi: 10.1016/j.ceramint.2018.04.066

[25]

Zhou Y M, Song W T, Zhang L J, Tao S Y. J. Mater. Chem. A, 2018, 6(26): 12298-12307. doi: 10.1039/C8TA01286E

[26]

CAO Xiao-Rong, HU Ming-Jiang. Chinese J. Anal. Chem., 2016, 44(10): 1555-1561. doi: 10.11895/j.issn.0253-3820.160283

曹小荣, 胡明江. 分析化学, 2016, 44(10): 1555-1561. doi: 10.11895/j.issn.0253-3820.160283

[27]

Varshney M, Sharma A, Chae K H, Kumar S, Won S O. J. Phys. Chem. Solids, 2018, 119: 242-250. doi: 10.1016/j.jpcs.2018.04.007

[28]

Tomas C, Alexander H, Christopher C. Mater. Sci. Eng. A, 2000, 286(1): 169-178. doi: 10.1016/S0921-5093(00)00625-0

[29]

Zhang B X, Zhang Y B, Luo Z H, Han W J, Qiu W F, Zhao T. ACS Omega, 2018, 3(4): 4688-4694. doi: 10.1021/acsomega.8b00098

[30]

Sun G X, Liu F T, Bi J Q, Wang C A. J. Alloy. Compd., 2015, 649: 788-792. doi: 10.1016/j.jallcom.2015.03.068

[31]

Liu G D, Lin Y H. Anal. Chem., 2005, 77(18): 5894-5901. doi: 10.1021/ac050791t

[32]

ZHANG Ying, SONG Xiu-Qin. Chemistry, 2010, 73(1): 71-74

张滢, 宋秀芹. 化学通报, 2010, 73(1): 71-74

[33]

Parham H, Rahbar N. J. Hazard. Meter., 2010, 177(1-3): 1077-1084. doi: 10.1016/j.jhazmat.2010.01.031

[34]

Tadele H, Mulu B, Abraha T, Mekonnen T, Amaha W, Berhanu M, Saini R C. Momona Ethiopian J. Sci., 2017, 9(1): 76-89. doi: 10.4314/mejs.v9i1.6

[35]

Mani G, Chen S M, Veerappan M, Muthumariappan A, Sakthivel K, Boopathi S. Microchim. Acta, 2017, 184(3): 725-733. doi: 10.1007/s00604-016-2062-6

[36]

Zhou J H, Deng C Y, Si S H, Wang S E. Microchim. Acta, 2011, 172(1-2): 207-215. doi: 10.1007/s00604-010-0483-1

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目录

静电纺丝法制备氧化锆纳米纤维修饰玻碳电极用于甲基对硫磷的检测

于皓, 万正妍, 朱国栋, 戴勇, 王彦博, 刘建允

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