首页 杂志概况 投稿须知 在线投稿 在线阅读 征订启事 广告服务 行业资讯 企业动态 资料中心  专访报道 会展信息 ENGLISH

引用本文:   崔敏, 任聚杰, 邢逸飞, 张聪, 李娜, 余旭东, 籍雪平. 负载钯铜三维还原氧化石墨烯电化学传感器检测对硝基苯酚. 分析化学, 2019, 47(4): 605-612. doi:  10.19756/j.issn.0253-3820.181623 [复制]

Citation:   CUI Min , REN Ju-Jie , XING Yi-Fei , ZHANG Cong , LI Na , YU Xu-Dong , JI Xue-Ping . An Electrochemical Sensor Based on Palladium-Copper Nanoparticles/Three-Dimensional Reduced Graphene Oxide for Detection of p-Nitrophenol. Chinese Journal of Analytical Chemistry, 2019, 47(4): 605-612. doi: 10.19756/j.issn.0253-3820.181623 [复制]

负载钯铜三维还原氧化石墨烯电化学传感器检测对硝基苯酚

收稿日期: 2018-09-30

基金项目: 本文系国家自然科学基金项目(No.81872669)、河北省教育厅科研项目(No.ZD2018037)和河北科技大学博士启动基金(No.1181157)资助

An Electrochemical Sensor Based on Palladium-Copper Nanoparticles/Three-Dimensional Reduced Graphene Oxide for Detection of p-Nitrophenol

Received Date:  2018-09-30

Fund Project:  This work was supported by the National Natural Science Foundation of China (No. 81872669), the Research Foundation of Education Department of Hebei Province of China (No. ZD2018037) and the Doctoral Starting up Foundation of Hebei University of Science and Technology, China (No. 1181157).

构建了基于负载钯铜纳米粒子的三维还原氧化石墨烯复合材料的对硝基苯酚电化学传感器。利用含钯离子、铜离子的溶液与氧化石墨烯(GO),通过水热法合成负载钯铜纳米粒子的三维还原氧化石墨烯([PdCu/3DRGO]),利用扫描电镜(SEM)、X射线衍射(XRD)、能谱分析(EDS)和傅里叶变换红外(FT-IR)光谱对材料进行了表征;将复合材料滴涂于玻碳电极(GCE)表面制成修饰电极([PdCu/3DRGO]/GCE),采用循环伏安法(CV)、交流阻抗法(EIS)研究了修饰电极的电化学行为。在优化的实验条件下,利用差分脉冲伏安法(DPV)、时间电流曲线法(i-t)等技术对硝基苯酚(4-NP)进行了检测,表现出良好的性能,检出限为0.050 μmol/L (S/N=3),灵敏度为0.372 μA/(μmol/L·cm2),线性范围为10~3000 μmol/L。传感器的稳定性好,抗干扰性能强,水中常见无机离子和结构类似物不干扰对4-NP的测定。

关键词:   电化学传感器, 对硝基苯酚, 钯铜纳米粒子, 还原氧化石墨烯
Key words:   Electrochemical sensor, p-Nitrophenol, Palladium-copper nanoparticles, Reduced graphene oxide
[1]

Shen W J, Liu W D, Zhang J, Tao J, Deng H H, Cao H, Cui Z L. Bioresource Technol.,2010,101(19):7516-7522

[2]

Samuel M S, Sivaramakrishna A, Mehta A. J. Environ. Health Sci.,2014,12:53

[3]

Loučka T, Došek M, Kǐíženecká S, Janoš P. J. Electroanal. Chem.,2018,823:580-587

[4]

Chen Z J, Niu Y Y, Zhao S, Khan A, Ling Z M, Chen Y, Liu P, Li X K. Biosens. Bioelectron.,2016,85:860-868

[5]

Balasubramanian P, Balamurugan T S T, Chen S M, Chen T W. J. Hazard. Mater.,2019,361:123-133

[6]

Zhang W, Wilson C R, Danielson N D. Talanta,2008,74(5):1400-1407

[7]

Hofmann D, Hartmann F, Herrmann H. Anal. Bioanal. Chem.,2008,391(1):161-169

[8]

Giribabu K, Suresh R, Manigandan R, Kumar S P, Muthamizh S, Munusamy S, Narayanan V. Microchim. Acta,2014,181 (15-16):1863-1870

[9]

Guo X F, Wang Z H, Zhou S P. Talanta,2004,64 (1):135-139

[10]

Wu J W, Wang Q, Umar A, Sun S H, Huang L, Wang J Y, Gao Y S. New J. Chem.,2014,38(9):4420-4426

[11]

Li J H, Kuang D Z, Feng Y L, Zhang F X, Xu Z F, Liu M Q. J. Hazard. Mater.,2012,201:250-259

[12]

Shi Q F, Diao G W. Electrochim. Acta,2011,59:399-405

[13]

Abaker M, Dar G N, Umar A, Zaidi S A, Ibrahim A A, Baskoutas S, Alhajry A. Sci. Adv. Mater.,2012,8(4):893-900

[14]

Nie X W, Jiang X, Wang H Z, Luo W J, Janik M J, Chen Y G, Guo X W, Song C S. ACS Catal.,2018,8(6):4873-4892

[15]

Wang Z Z, Zhang H Y, Chen L L, Miao S S, Wu S J, Hao X F, Zhang W X, Jia M J. J. Phys. Chem. C,2018,122(24):12975-12983

[16]

Rowley-Neale S J, Randviir E P, Abo Dena A S, Banks C E. Appl. Mater. Today,2018,10:218-226

[17]

Hu C G, Zhai X Q, Zhao Y, Bian K, Zhang J, Qu L T, Zhang H M, Luo H X. Nanoscale,2014,6(5):2768-2775

[18]

Zhang C, Zhang Y Y, Du X, Chen Y, Dong W H, Han B K, Chen Q. Talanta,2016,159:280-286

[19]

Wen Y P, Wen W, Zhang X H, Wang S F. Biosens. Bioelectron.,2016,79:894-900

[20]

Giribabu K, Oh S Y, Suresh R, Kumar S P, Manigandan R, Munusamy S, Gnanamoorthy G, Kim J Y, Yun S H, Narayanan V. Microchim. Acta.,2016,183(8):2421-2430

[21]

Zhang Y Y, Chu G L, Guo Y M, Zhao W P, Yang Q Q, Sun X. J. Electroanal. Chem.,2018,824:201-206

[22]

Teymourian H, Salimi A, Khezrian S. Biosens. Bioelectron.,2013,49:1-8

[23]

Tootoonchi A, Davarani S S H, Sedghi R, Shaabani A, Moazami H R. J. Electrochem. Soc.,2018,165(3):B150-B159

[24]

Ahmad K, Mohammad A, Mathur P, Mobin S M. Electrochim. Acta,2016,215:435-446

[25]

Sinhamahapatra A, Bhattacharjya D, Yu J S. RSC Adv.,2015,5(47):37721-37728

[26]

Xu Y H, Wang Y L, Ding Y P, Luo L Q, Liu X J, Zhang Y X. J. Appl. Electrochem.,2013,43(7):679-687

[27]

Tang Y H, Huang R, Liu C B, Yang S L, Lu Z Z, Luo S L. Anal. Methods,2013,5(20):5508-5514

计量
  • PDF下载量(72)
  • 文章访问量(381)
  • HTML全文浏览量(4)

目录

负载钯铜三维还原氧化石墨烯电化学传感器检测对硝基苯酚

崔敏, 任聚杰, 邢逸飞, 张聪, 李娜, 余旭东, 籍雪平

Figures and Tables