首页 杂志概况 投稿须知 在线投稿 在线阅读 征订启事 广告服务 行业资讯 企业动态 资料中心  专访报道 会展信息 ENGLISH

引用本文:   郭家旺, 刘琴, 栗大超, 林园, 王倩. 生物模板法制备的PdPt合金纳米管用于检测H2O2. 分析化学, 2019, 47(11): 1794-1802. doi:  10.19756/j.issn.0253-3820.191457 [复制]

Citation:   GUO Jia-Wang , LIU Qin , LI Da-Chao , LIN Yuan , WANG Qian . Synthesis of PdPt Nanotubes Using Biotemplate and Their Application in Detection of H2O2. Chinese Journal of Analytical Chemistry, 2019, 47(11): 1794-1802. doi: 10.19756/j.issn.0253-3820.191457 [复制]

生物模板法制备的PdPt合金纳米管用于检测H2O2

通讯作者:  林园, linyuan@ciac.ac.cn

收稿日期: 2019-07-29

基金项目: 本文系吉林省自然科学基金项目(No.20170101189JC)和天津大学精密测试技术及仪器国家重点实验室开放基金资助

Synthesis of PdPt Nanotubes Using Biotemplate and Their Application in Detection of H2O2

Corresponding author:  LIN Yuan , linyuan@ciac.ac.cn

Received Date:  2019-07-29

Fund Project:  This work was supported by the Jilin Province Science and Technology Development Program (No. 20170101189JC) and State Key Laboratory of Precision Measuring Technology and Instruments (Tianjin University).

利用烟草花叶病毒(TMV)外表面的拓扑结构以及均匀分布的精氨酸残基,基于生物模板法,合成了钯(Pd)纳米管,进一步通过溴离子(Br-)诱导的电置换方法合成了PdPt合金纳米管(TMV/PdPtNT)。TMV/Pd70Pt30NT的一维结构和管状结构使此材料具有高电化学活性的比表面积和良好的导电性。这些结构优势与PdPt双金属电子效应协同,提高了PdPt合金的催化活性。采用TMV/Pd70Pt30NT修饰丝网印刷电极(SPE/TMV/Pd70Pt30NT),检测H2O2的线性范围为8.8×10-7~1.0×10-3 mol/L,检出限为2.0×10-7 mol/L。本方法对H2O2的检测灵敏度达到493 A/(cm2·mol),高于Pd纳米管(TMV/PdNT)和商业Pt/C。

关键词:   烟草花叶病毒, 钯铂合金, 纳米管, 过氧化氢, 电化学传感器
Key words:   Tobacco mosaic virus, Platinum-palladium Alloy, Nanotube, Peroxide hydrogen, Electrochemical sensor
[1]

Dickinson B C, Chang C J. Nat. Chem. Biol.,2011,7:504-511

[2]

Hampton M B, Vick K A, Skoko J J, Neumann C A. Antioxid. Redox Sign.,2017,28(7):591-608

[3]

Christine C Winterbourn. Antioxid.Redox Sign.,2018,29(6):541-551

[4]

Wen F, Dong Y, Feng L, Wang S, Zhang S, Zhang X. Anal. Chem.,2011,83(4):1193-1196

[5]

Shi Q, Song Y, Zhu C, Yang H, Du D, Lin Y. ACS Appl. Mater. Interfaces,2015,7(43):24288-24295

[6]

Zhang Y, Bai X, Wang X, Shiu K K, Zhu Y, Jiang H. Anal. Chem.,2014,86(19):9459-9465

[7]

Guan H, Liu Y, Bai Z, Zhang J, Yuan S, Zhang B. Mater. Chem. Phys.,2018,213:335-342

[8]

Zhang R, Chen W. Biosens. Bioelectron,2017,89(1):249-268

[9]

Xiao T, Wu F, Hao, Zhang M, Yu P, Mao L. Anal. Chem.,2017,89(1):300-313

[10]

Ju J, Chen W. Anal. Chem.,2015,87(3):1903-1910

[11]

Li H, Zhao H, He H, Shi L, Cai X, Lan M. Sens. Actuators B,2018,260:174-182

[12]

Sardesai N P, Ganesana M, Karimi A, Leiter J C, Andreescu S. Anal. Chem.,2015,87(5):2996-3003

[13]

Kergoat L, Piro B, Simon D T, Pham M C, Noël V, Berggren M. Adv. Mater.,2014,26:5658-5664

[14]

Lv H, Chen X, Xu D, Hu Y, Zheng H, Suib S L, Liu B. Appl. Catal. B,2018,238:525-532

[15]

Liu H, Liu K, Zhong P, Qi J, Bian J, Fan Q, Ren K, Zheng H, Han L, Yin Y, Gao C. Chem. Mater.,2018,30(21):7744-7751

[16]

Zhang B W, Yang H L, Wang Y X, Dou S X, Liu H K. Adv. Energy Mater.,2018,8:1703597

[17]

Lu Y, Jiang Y, Chen W. Nano Energy,2013,2(5):836-844

[18]

Hong W, Wang J, Wang E. Small,2014,10(16):3262-3265

[19]

Li Y, Niu X, Tang J, Lan M, Zhao M. Electrochim. Acta,2014,130:1-8

[20]

Bruckman M A, Kaur G, Lee L A, Xie F, Sepulveda J, Breitenkamp R, Zhang X, Joralemon M, Russell T P, Emrick T, Wang Q. ChemBioChem,2008,9:519-523

[21]

Zhao X, Chen L, Luckanagul J A, Zhang X, Lin Y, Wang Q. ChemBioChem,2015,16:1279-1283

[22]

Guo J, Zhao X, Hu J, Lin Y, Wang Q. Mol. Pharmaceut.,2018,15(8):2946-2953

[23]

He J, Niu Z, Tangirala R, Wang J Y, Wei X, Kaur G, Wang Q, Jutz G, Böker A, Lee B, Pingali S V, Thiyagarajan P, Emrick T, Russell T P. Langmuir,2009,25(9):4979-4987

[24]

Yang X, Yang Q, Xu J, Lee C S. J. Mater. Chem.,2012,22:8057-8062

[25]

Sawant T V, McKone J R. J. Phys. Chem. C,2019,123(1):144-152

[26]

Guo S, Wen D, Zhai Y, Dong S, Wang E. ACS Nano,2010,4(7):3959-3968

[27]

Liu W, Hiekel K, Hübner R, Sun H, Ferancova A, Sillanpää M. Sens. Actuators B,2018,255(2):1325-1334

[28]

Wen Z, Ci S, Li J. J. Phys. Chem. C,2009,113(31):13482-13487

[29]

Xu F, Sun Y, Zhang Y, Shi Y, Wen Z, Li Z. Electrochem. Commun.,2011,13(10):1131-1134

[30]

Liu Y, Wang D, Xu L, Hou H, You T. Biosens. Bioelectron,2011,26(11):4585-4590

计量
  • PDF下载量(31)
  • 文章访问量(458)
  • HTML全文浏览量(6)

目录

生物模板法制备的PdPt合金纳米管用于检测H2O2

郭家旺, 刘琴, 栗大超, 林园, 王倩

Figures and Tables